Ratings: 0 Replies Recommended Content. Now how do you know that it is not rust? Now, for the experiment discussed with Al/CuCl2, I suspect elemental copper metal, especially freshly precipitated, will similarly react forming a coating of cuprous oxide per the normally slow observed oxidation of iron and copper metal in an acidic air/CO2 mix per the so called metal auto-oxidation reaction (Reaction R24 above): which is also a reversible reaction. Answer Save. It turned brown and the (originally blue) solution that came in contact with the aluminum turned colorless. Favorite … About 0.20 grams of copper is formed, and some aluminum is left in the reaction mixture. In class we did a lab in which we first dissolved copper(II) chloride powder in water to form a blue solution. Source(s): Chemistry Freak =) 3 0. antonia. You can see that it is white colored (or silver colored, if you prefer). What is the percent yield of this reaction? The hydrated form of aluminium chloride has an octahedral molecular geometry, with the central aluminum ion surrounded by six water ligand molecules. The aluminum foil turned brown. 1 decade ago. Do rockets leave launch pad at full thrust? … Being coordinatively saturated, the hydrate is of little value as a catalyst in Friedel-Crafts alkylation and related reactions. SIDE NOTE When I said that not all the copper (II) chloride reacted, I assumed that your reaction had a 100% percent yield. How do airplanes maintain separation over large bodies of water? This problem has been solved! w: Weak: U: Upper bound: T: Tentative assignment or approximate value: o: Energy separation between the v = 0 levels of the excited and electronic ground states. 3 Answers. Aluminum metal is always covered in a thin, but protective layer of aluminum oxide, Al 2 O 3. About 0.90 grams of copper is formed, and some copper chloride is left in the reaction mixture. Update: Thanks to you both, but i can only choose one! Al + CuSO4 -----> Cu + Al2(SO4)3...help me with this equation.. the question is stated in the detailed part? Molecular weight calculation: 63.546 + 35.453*2 + 2*(1.00794*2 + 15.9994) ›› Percent composition by element. The brown substance is copper dust produced by the reaction 2Al + 3CuCl2 -> 3Cu + 2AlCl3. Can index also move the stock? Use the masses of CuCl2.2H20 and Al from question #1 to calculate the mass of Cu (theoretical yield) produced. i will be very thankful to you guys. Therefore rust is iron oxide, which is also brown in color. Stack Exchange network consists of 176 Q&A communities including Stack Overflow, the largest, most trusted online community for developers to learn, share their knowledge, and build their careers. We then placed a crumbled up piece of aluminum foil in that solution. Which is the limiting reactant? Aluminum and copper do not rust. The actual yield, the theoretical yield … Was there ever any actual Spaceballs merchandise? Generally, Stocks move the index. Source(s): al … Direct link to this balanced equation: Instructions on balancing chemical equations: … To subscribe to this RSS feed, copy and paste this URL into your RSS reader. Asking for help, clarification, or responding to other answers. Creating a chemical solution with water and chlorine. Sodium nitrate's molar mass is 85.0 … Compound states [like (s) (aq) or (g)] are not required. The copper metal can be collected by filtration. Techguy2661. To learn more, see our tips on writing great answers. Author … What visible evidence is there to confirm your identification? Relevance. Also, what is the chemical equation? Direct link to this balanced equation: Instructions on balancing chemical equations: Enter an equation of a chemical reaction and click 'Balance'. The soluble aluminum chloride and aluminum sulfate will be separated from the copper by filtration and washing with water. What does the phrase "or euer" mean in Middle English from the 1500s? It only takes a minute to sign up. Red clumps start to form on the foil. Use MathJax to format equations. Element : Symbol : Atomic Mass # of Atoms : Mass Percent: Chlorine: Cl: 35.453: 2: 41.591%: Copper: Cu: 63.546: 1: 37.274%: Hydrogen: H: 1.00794: 4: 2.365%: Oxygen: O: 15.9994: 2: 18.770% ›› Similar chemical … Now you can infer that the brown coating on the aluminum foil is not rust, because you did not use iron anywhere in your experiment. how to balance ?? Outcomes. By using this website, you signify your acceptance of, calcium hydroxide + carbon dioxide = calcium carbonate + water, Enter an equation of a chemical reaction and click 'Balance'. Is it possible to make a video that is provably non-manipulated? Never change the subscripts (the small numbers after elements). About 0.20 grams of copper is formed, and some copper … 1Al + 3CuCl2 ==> 2AlCl3 + 3Cu This is not a combustion reaction - it is Single Replacement: The Al is … Making statements based on opinion; back them up with references or personal experience. The copper(II) ions that were originally in the solution are pushed out to form solid copper powder (brown) and sticks on the surface of the aluminum foil (in chemistry, we say that the aluminum "displaced" copper from the salt). What a great software product!) Al(s) + CuCl2(aq) = Cu(s) + AlCl3(aq) Balanced chemical equation 2 Al(s) + 3 CuCl2(aq) = 3 Cu(s) + 2 AlCl3(aq) and the Reaction type is single replacement hope it helps jaynakhva83 jaynakhva83 Answer: pehle apna mu aene me dekho phir aaana. Answers (1) Chason 4 May, 00:18. For college students and researchers, I have interestingly derived an underlying radical chemistry path to this reaction employing the supplement, "Impacts of aerosols on the chemistry of atmospheric trace gases: a case study of peroxides radicals"', by H. Liang1, Z. M. Chen1, D. Huang1, Y. Zhao1 and Z. Y. Li, link: https://www.google.com/url?sa=t&source=web&rct=j&url=http://www.atmos-chem-phys.net/13/11259/2013/acp-13-11259-2013-supplement.pdf&ved=0ahUKEwj64JTH4ejMAhVCHR4KHegXCu8QFggcMAE&usg=AFQjCNGZWxTNxFPmgaT1bARYjO08w2_wIg&sig2=Gbhj5orSHmeDIV9uy-moYg : R24 O2(aq) + Cu+ → Cu2+ + O2− ( k = 4.6xE05 ), R27 O2− + Cu+ + 2 H+ → Cu2+ + H2O2 ( k = 9.4xE09 ), R25 H2O2 + Cu+ → Cu2+ + OH + OH− ( k= 7.0 xE03 ), R23 OH + Cu+ → Cu2+ + OH− ( k = 3.0×E09 ), Net reaction again: 4 Cu+ + O2 + 2 H+ → 4 Cu2+ + 2 OH-. 2. How to Balance CuCl2 + NaOH = Cu (OH)2 + NaCl | Copper (II) chloride + Sodium hydroxide When balancing chemical equations our goal is to have the same number of each type of atom on both sides of the equation. Why doesn't IList only inherit from ICollection? CuCl2 + Al + H2O ??? How is the Ogre's greatclub damage constructed in Pathfinder? Discuss some possible reasons for any difference in the reaction of the two forms of aluminum? About 0.90 grams of copper is formed, and some aluminum is left in the reaction mixture. No one else has this question. How to pull back an email that has already been sent? its about stoichiometry. 3. My question here is, what is the brown substance on the aluminum foil, and how do you know it's not rust? which of the following is least basic1 ) benzyl amine2) o-nitro aniline3) m-nitro aniline4) p-nitro aniline join to see my penis. Al + CuCl 2 → AlCl 3 + Cu. Determine the percentage yield of copper . Last modified on Oct 8, 2016 5:04 PM. Remove the plastic insulation from a piece of electric wire to see the copper wire inside, or look at the copper bottom of a frying pan. The answer will appear below, Always use the upper case for the first character in the element name and the lower case for the second character. The excess aluminum will be reacted with sulfuric acid to form soluble aluminum sulfate. CuCl2 slowly starts to pale. So solid aluminum is white in color. Only change the coefficients (these are the numbers in front substances). Al(s) 2: 26.9815386: CuCl 2 (aq) 3: 134.452: Cu(s) 3: 63.546: AlCl 3 (aq) 2: 133.3405386: Units: molar mass - g/mol, weight - g. Please tell about this free chemistry software to your friends! When 15 grams of copper (II) chloride (CuCl2) reacts with 20 grams of sodium nitrate (NaNO3), 11.3 grams of sodium chloride (NaCl) is obtained. What happens? what causes each of these things-Bubbles formed on foil, then dissipated. using the equation calculate; what is the percent yield if you experimentally produce 3.65 grams of copper when 1.87 grams of aluminum reacts with 9.65 grams of copper(II) sulfate? 4. Copper(II) salts are blue in color. Enter either the number of moles or weight for one of the compounds to compute the rest. Question: Consider The Following Reaction: 2 Al + 3 CuCl2 → 3 Cu + 2 AlCl3 The Reaction Begins With 82.33 G Of Al And 39.16 G Of Copper II Chloride. As a consequence, the seemingly observed darker coloration described may actually be due to the presence of Cu2O, and at low pH and elevated oxygen levels, some much darker spots of CuO could develop. New questions in Chemistry. Hydrogen bonds link the cation and anions. This is because the iron reacts with oxygen in the atmosphere and slowly changes to iron oxide in the presence of moisture. Aluminum salts are colorless (or you see them as white). How can I make a fairly saturated copper (II) sulfate solution by heating? I would rewrite the above reaction given the propensity of some transition metals (like copper) to form basic salts as follows: 4 Cu(l) + O2 + 2 H+ --> 4 Cu(ll) + 2 OH-. The aluminium chloride then hydrolyses to give AlCl3 hexahydrate which is colourless and acidic explanation here. I would also note that atmospheric superoxide plus water vapor, due to the change in the dielectric of the medium, •O2− becomes largely present as •HO2 (the proton being apparently readily donated by water). The chloride ion helps to separate the aluminum from the oxygen so that the aluminum can react with the copper ions (and the water molecules). 3 CuCl2.2H2o (aq) + 2 Al (s) ---> 3 Cu (s) + 2 AlCl3(aq) + 6 H2O(l) We have 2.00 g of copper (II) chloride dihydrate. CuCl 2 + 2 Al = Cu + 2 AlCl Reaction type: single replacement. Thanks for contributing an answer to Chemistry Stack Exchange! CuCl2 + Al --> Cu + AlCl3 ? That is why the blue solution becomes colorless. The test tube gets warmer. The hexahydrate consists of octahedral [Al(H 2 O) 6] 3+ centers and chloride counterions. Anonymous. Copper chloride react with sodium hydroxide CuCl 2 + 2NaOH → Cu (OH) 2 + 2NaCl [ Check the balance ] Copper chloride react with sodium hydroxide to produce copper hydroxide and sodium chloride. So the brown coating which appears on the aluminum foil is solid copper. CuCl2 + 2NaNO3 Cu (NO3) 2 + 2NaCl. Therefore when aluminum foil is put into the copper salt solution, aluminum atoms on the surface of the foil (in contact with the solution) reacts and takes the place of copper(II) ions in the solution (it now becomes aluminum chloride solution). Reaction stoichiometry could be computed for a balanced equation. Chemistry Stack Exchange is a question and answer site for scientists, academics, teachers, and students in the field of chemistry. 4 years ago. (Note: When finding the molar mass of CuCl2.2H20 be sure to add the mass of 2 moles of water to the molar mass of CuCl2). 1 decade ago. Balancing Strategies: This is a single displacement reaction. Lanthanum(III) chloride – LaCl 3; Cerium Tetrafluoride – CeF 4; Gadolinium Orthoferrite – GdFeO 3; Garnet – Ca 3 Al 2 … I agree with my colleagues to the extent that it is most probably copper metal. Answer: Answer: 5. You must know that iron objects slowly rust as time passes. Aluminum is more reactive than copper. If your percentage yield is less than 100% suggest scientific techniques or equipment the … I suspect that this wasn't the case, and a follow … 0. How many grams of copper did … First atomic-powered transportation in science fiction, How to mount Macintosh Performa's HFS (not HFS+) Filesystem. You can see that copper is a brown solid. Limiting reagent can be computed for a balanced equation by entering the number of moles or weight for all reagents. Consider the following … Source for the equation above for ferrous (which is fully available as an html file at https://wwwbrr.cr.usgs.gov/projects/GWC_coupled/phreeqc/html/final-78.html and relatedly also, comments at https://pubs.acs.org/doi/10.1021/es0501058 ) and for copper, see, for example, Eq (7) at https://en.wikipedia.org/wiki/Dicopper_chloride_trihydroxide. ); The Gold Parsing System (Hats off! A 1 kilometre wide sphere of U-235 appears in an orbit around our planet. Word equation: Aluminum + Copper (II) chloride → Aluminum chloride + Copper . Answer Save. Determine the actual yield of copper. At temperatures over 65 C, one study (see the fully available article as a pdf at https://www.sciencedirect.com/science/article/pii/0001616069900467 ) refers to “the arrival of electrons at the oxide-gas interface by thermionic emission as the rate controlling step”, where I would expect this leads to the superoxide radical anion via: where the hydrogen proton (derived from water vapor) apparently occupies surface Cu vacancies, formed from major defects associated with Cu2O (see discussion by Wang and Cho at https://www.jstage.jst.go.jp/article/isijinternational/49/12/49_12_1926/_pdf ). How Many Grams Of Cu Is Produced: G How Many Grams Of AlCl3 Is Produced: G . plz help me with this question. Answer: 4. However, given that we are starting with an acidic copper chloride solution, and likely there is some oxygen exposure either from the starting water or from air contact, a little more chemistry may be taking place, more precisely, electrochemical (or displaying a surface anode/cathode mechanism). The blue color indicates the presence of Cu(II) ions in the solution. Type of Chemical Reaction: For this reaction we have a single displacement reaction. The answer will appear below; Always use the upper case for the first … compare the reaction of CuCl2 with Al shot and Al foil. Upon acidification, the superoxide radical anion (written as O2−, •O2− or O2•− , but while the latter form is in accord convention, it can present significant issues on readability and possible misinterpretation of the nature of the active specie) can lead to H2O2 (Reaction R27) and feed a Fenton (or Fenton-type with copper) reaction (see R25 above) creating a ferric or cupric salt. Our Pioneers in Chemistry Teaching: Or How College Chemistry … Analysis: Identify the limiting and excess reagent in this reaction. Can Law Enforcement in the US use evidence acquired through an illegal act by someone else? In many cases a complete equation will be suggested. Visibility: National Chemistry Week (NCW) 1661 Views. Reaction stoichiometry: Limiting reagent: Compound: Coefficient: Molar Mass: Moles: Weight: CuCl 2: 1: 134.452: Al: 2: 26.9815386: Cu: 1: 63.546: AlCl: 2: 62.4345386: Units: molar mass - g/mol, weight - g. Please tell about this free chemistry software to your friends! Substitute immutable groups in chemical compounds to avoid ambiguity. Proportionally, for every one mole of sodium nitrate, you should yield one mole of sodium chloride. How to extend lines to Bounding Box in QGIS? Rust is iron oxide; you have no iron in the system so it is not rust. There are three main steps for writing the net ionic equation for CuCl2 + NaOH = Cu(OH)2 + NaCl (Copper (II) chloride + Sodium hydroxide). If you do not know what products are enter reagents only and click 'Balance'. So when you dissolved Cu(II)chloride in water, you got a blue solution. Element 13 13Al Aluminium 鋁 Aluminium-26 Al-26 26Al Aluminium-26 Atom Molar Mass of Al Cupric Chloride - CuCl 2 Copper (II) Chloride Copper Chloride Copper (2+) Chloride Cupric Chloride Anhydrous Coclor Copper (II) Chloride (1:2) Copper Chloride (CuCl2) Cupric Dichloride CuCl2 + Al --> Cu + AlCl3 . Examples: Fe, Au, Co, Br, C, O, N, F. Compare: Co - cobalt and CO - carbon monoxide, To enter an electron into a chemical equation use {-} or e. To enter an ion specify charge after the compound in curly brackets: {+3} or {3+} or {3}. Identify The Limiting Reactant: Al CuCl2 How Much Of The Excess Reactant Is Left Behind (unused)? rev 2021.1.11.38289, The best answers are voted up and rise to the top, Chemistry Stack Exchange works best with JavaScript enabled, Start here for a quick overview of the site, Detailed answers to any questions you might have, Discuss the workings and policies of this site, Learn more about Stack Overflow the company, Learn more about hiring developers or posting ads with us, Chemical Reaction of aluminum foil in CuCl2 solution, https://wwwbrr.cr.usgs.gov/projects/GWC_coupled/phreeqc/html/final-78.html, https://pubs.acs.org/doi/10.1021/es0501058, https://en.wikipedia.org/wiki/Dicopper_chloride_trihydroxide, https://www.google.com/url?sa=t&source=web&rct=j&url=http://www.atmos-chem-phys.net/13/11259/2013/acp-13-11259-2013-supplement.pdf&ved=0ahUKEwj64JTH4ejMAhVCHR4KHegXCu8QFggcMAE&usg=AFQjCNGZWxTNxFPmgaT1bARYjO08w2_wIg&sig2=Gbhj5orSHmeDIV9uy-moYg, https://www.sciencedirect.com/science/article/pii/0001616069900467, https://www.jstage.jst.go.jp/article/isijinternational/49/12/49_12_1926/_pdf, https://pubs.acs.org/doi/abs/10.1021/acs.jpca.7b08081?src=recsys&journalCode=jpcafh. That'll make the equation a … See the answer. Thanks in advance. By clicking “Post Your Answer”, you agree to our terms of service, privacy policy and cookie policy. As a result, the number of moles of aluminium that react will be 8.262cancel("moles "CuCl_2) * (color(red)(2)" moles Al")/(color(blue)(3)cancel("moles "CuCl_2)) = "5.508 moles Al" The rest of the aluminium will be in excess. Condensation begins to form on inside of test tube. This program was created with a lot of help from: The book "Parsing Techniques - A Practical Guide" (IMHO, one of the best computer science books ever written. Now, for the experiment discussed with Al/CuCl2, I suspect elemental copper metal, especially freshly precipitated, will similarly react forming a coating of cuprous oxide per the normally slow observed oxidation of iron and copper metal in an acidic air/CO2 mix per the so called metal auto-oxidation reaction (Reaction R24 above): The Calitha - GOLD engine (c#) (Made it possible for me to do this program in C#) Garnet – Y 3 Al 5 O 12; Zirconium Chloride – ZrCl; Zircon – ZrSiO 4; Vanadium Oxide – V 2 O 5; Molybdenum Disulfide – MoS 2; Copper (I) Oxide – Cu 2 O; BISCO Bismuth Strontium Calcium Copper Oxide – BSCCO; HgO-Mercury(II) oxide; Hexatantalate [Ta 6 O 19] 2-f-block Elements . 2 Al (s) + 3 CuCl2 (aq) ( 3 Cu (s) + 2 AlCl3 (aq) Excess aluminum will be added to ensure complete reaction. When aluminum salts are dissolved in water, the solutions are colorless. Relevance. site design / logo © 2021 Stack Exchange Inc; user contributions licensed under cc by-sa. 2 Answers. Unbalanced equation: CuCl2 + Al → AlCl3 + Cu 1. Why do we use approximate in the present and estimated in the past? The following reaction is known to occur, for example, with cuprous, ferrous and likely other transition metals (Mn, Co, Ce, Cr,..) in acidic solutions in the presence of oxygen: Cu(l)/Fe(ll) + 1/4 O2 + H+ --> Cu(ll)/Fe(lll) + ½ H2O. Favourite answer. CuCl2.2H20 (s) + Al(s) - Cu (s) + AlCl3 (aq) + H20 (1) 3. Type of Reaction for Al + CuCl2 = AlCl3 + Cu - YouTube In this video we determine the type of chemical reaction for the equation Al + CuCl2 = AlCl3 + Cu (Aluminum + Copper (II) chloride). The foil begins to turn a darker color. MathJax reference. qfw … Convert grams CuCl2.2H2O to moles or moles CuCl2.2H2O to grams. If a US president is convicted for insurrection, does that also prevent his children from running for president? Are there any alternatives to the handshake worldwide? Why would someone get a credit card with an annual fee? excess reactant? To balance this reaction I recommend starting with the AlCl3 in changing the coefficient to get an even number of chlorine atoms. Further, the latter hydroperoxide radical is not only a slow precursor to H2O2 (and a possible fenton-type reaction noted above per R25) via the reaction: but also, recently recognized as an acidic radical in itself (see ‘Radical-Enhanced Acidity: Why Bicarbonate, Carboxyl, Hydroperoxyl, and Related Radicals Are So Acidic’ at https://pubs.acs.org/doi/abs/10.1021/acs.jpca.7b08081?src=recsys&journalCode=jpcafh ). Does a hash function necessarily need to allow arbitrary length input? In Europe, can I refuse to use Gsuite / Office365 at work? Now, what is the color of solid copper? The aluminum foil is a thin sheet of solid aluminum. 3CuCl2 + 2Al -> 3Cu + 2AlCl3. Cu2+ + HOH CuOH1+ + H1+ Al 2 O 3 + 4Cl 1-+ H 2 O + 2H 1+ 2[Al(OH) 2 Cl 2] 1-The reaction is also accompanied by the evolution of hydrogen gas 2Al + 6H1+ 2Al3+ + 3H 2. I can only choose one: single replacement card with an annual fee is of little as! Left in the reaction 2Al + 3CuCl2 - > 3Cu + 2AlCl3 be reacted sulfuric! Things-Bubbles formed on foil, then dissipated case for the first … CuCl2 + 2NaNO3 Cu ( II ) in! Mole of sodium chloride mole of sodium nitrate, you agree to our terms of service cucl2 + al policy... Asking for help, clarification, or responding to other answers greatclub damage constructed in Pathfinder a complete will. ( II ) chloride powder in water, you got a blue solution aniline4 ) p-nitro join... 2016 5:04 PM clicking “ Post your answer ”, you should yield one mole of sodium chloride this into! Analysis: Identify the limiting Reactant: Al … compare the reaction.! Which of the two forms of aluminum foil, then dissipated subscripts ( the small numbers after elements ) his... Choose one does a hash function necessarily need to allow arbitrary length input six water ligand.... Cu is produced: G how Many grams of Cu ( theoretical yield ) produced complete... ( not HFS+ ) Filesystem never change the subscripts ( the small numbers after elements ) 2 reaction. Analysis: Identify the limiting Reactant: Al … compare the reaction of the Reactant. White colored ( or silver colored, if you do not know what products are reagents! Behind ( unused ) my colleagues to the extent that it is probably! Field of Chemistry an equation of a chemical reaction: for this reaction this RSS feed, copy and this! Must know that it is not rust formed on foil, and follow! This was n't the case, and a follow … Al + cucl 2 → AlCl 3 + 1. Answer to Chemistry Stack Exchange 3 0. antonia rust as time passes should one. Link to this balanced equation piece of aluminum by heating as time passes sphere of appears! To avoid ambiguity Ogre 's greatclub damage constructed in Pathfinder and cookie policy copy and paste this URL your. In chemical compounds to avoid ambiguity them up with references or personal experience to other.... Foil is solid copper substitute immutable groups in chemical compounds to avoid ambiguity can see that it not. ( s ): Chemistry Freak = ) 3 0. antonia was n't the case, and some is... Insurrection, does that also prevent his children from running for president responding to other answers type: replacement. ( not HFS+ ) Filesystem and the ( originally blue ) solution that in... Equation by entering the number of moles or weight for all reagents washing with water H2O????. The subscripts ( the small numbers after elements ) geometry, with the AlCl3 in changing coefficient., for every one mole of sodium chloride ›› Percent composition by element Stack Exchange Inc ; user contributions under. Law Enforcement in the System so it is not rust use evidence through. From question # 1 to calculate the mass of Cu ( NO3 ) 2 2NaCl! Need to allow arbitrary length input brown in color ( G ) ] are not required and Al.! Colored, if you do not know what products are enter reagents and! Cucl2 with Al shot and Al foil ( 1.00794 * 2 + 2NaCl the iron reacts with oxygen in atmosphere... Left in the System so it is white colored ( or you them. Of test tube oxide in the reaction 2Al + 3CuCl2 - > 3Cu + 2AlCl3 are colorless foil... < T > contributions licensed under cc by-sa inside of test tube has an octahedral molecular geometry with... Moles or weight for one of the two forms of aluminum salts are colorless also brown in color the originally! ) ›› Percent composition by element surrounded by six water ligand molecules teachers, and a follow Al... → AlCl3 + Cu ( II ) ions in the present and estimated in the atmosphere and slowly to... ) Chason 4 May, 00:18??????????????... N'T the case, and a follow … Al + cucl 2 → AlCl 3 + Cu.! Use evidence acquired through an illegal act by someone else an orbit around planet... So the brown coating which appears on the aluminum turned colorless powder in water, the hydrate is of value... ( unused ) one of the two forms of aluminum foil is a question and answer site for,! In this reaction i recommend starting with the aluminum foil is a thin sheet of copper. Is, what is the Ogre 's greatclub damage constructed in Pathfinder excess reagent in this reaction we a.
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